Asymptotic decay of the pair correlation function in molecular fluids: Application to hard rods

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Asymptotic decay of the pair correlation function in molecular fluids: application to hard rods.

We investigate the asymptotic decay of the total correlation function h (1,2) in molecular fluids. To this end, we expand the angular dependence of h (1,2) and the direct correlation function c (1,2) in the Ornstein-Zernike equation in a complete set of rotational invariants. We show that all the harmonic expansion coefficients h l1l2l) (r) are governed by a common exponential decay length and ...

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ژورنال

عنوان ژورنال: Physical Review E

سال: 2005

ISSN: 1539-3755,1550-2376

DOI: 10.1103/physreve.72.021202